Préparation d'acide acétique monochloré essentiellement pur

N° de brevet: EP1900719 (A1)
Date de publication: 2008-03-19
Inventeur(s): TIMMERMANS ROXANA STOENESCU DR [CH];KETTENBACH GERHARD DR [DE];
Demandeur(s): BUSS CHEMTECH AG [CH];
Classification: C07C51/377;C07C53/16;
N° de demande: EP20060018382 20060901 
Numéro(s) de priorité: EP20060018382 20060901 
A process for the manufacture of substantially pure monochloroacetic acid from a liquid chloroacetic acid mixture comprising monochloroacetic acid and dichloroacetic acid, in particular in an amount of 2 to 40 percent by weight, wherein said mixture, further mixed with a suspended hydrogenation catalyst, is mixed with hydrogen gas and the resulting mixture is brought to reaction in a reactor, which is characterized in that the reactor is a loop reactor comprising a gas and liquid recirculation system coupled via an ejector mixing nozzle, in which reactor the gas and liquid are circulated in co-current flow, and the mixing intensity introduced to the liquid phase is at least 50 W/l of liquid phase.

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