DÉRIVÉ DU FLUORÈNE, COMPOSÉ DE MÉTAL DE TRANSITION, CATALYSEUR POUR LA POLYMÉRISATION D'OLÉFINES ET PROCÉDÉ SERVANT À PRODUIRE UN POLYMÈRE D'OLÉFINE

N° de brevet: EP1900715 (A1)
Date de publication: 2008-03-19
Inventeur(s): FUNAYA MUNEHITO [JP];ENDO KOJI [JP];HIROTA NARITOSHI [JP];YAMAMURA YUICHI [JP];KAWAI KOJI [JP];
Demandeur(s): MITSUI CHEMICALS INC [JP];
Classification: C07C13/62;C07F17/00;C08F4/6592;C08F10/00;C07F7/00;
N° de demande: EP20060746820 20060524 
Numéro(s) de priorité: WO2006JP310391 20060524;JP20050152873 20050525 
Provided is a novel fluorene derivative which is useful as a catalyst component for olefin polymerization, a transition metal compound containing the fluorene derivative as a part of ligand, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing olefin polymer. The fluorene derivative is characterized by being represented by the following general formula [I]: wherein R 1 , R 2 , R 3 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , and R 14 are each selected from hydrogen, a hydrocarbon group, and a silicon-containing group, and may be the same as or different from each other, R 4 and R 13 are each selected from hydrogen, a hydrocarbon group, a silicon-containing group, a sulfur-containing group, an oxygen-containing group, a nitrogen-containing group, and a halogen-containing group, and may be the same as or different from each other, and adjacent substituents of R 1 to R 14 may be bonded to each other to form a ring, except that the case where R 4 and R 5 , and R 12 and R 13 are each bonded to each other to form a vinylene group. Also provided is a bridged metallocene compound having both of the skeleton and a cyclopentadiene skeleton.

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