RÉACTEUR POUR LA PRODUCTION DE CHLORE ET PROCÉDÉ DE PRODUCTION DE CHLORE

N° de brevet: EP1894885 (A1)
Date de publication: 2008-03-05
Inventeur(s): MORI YASUHIKO [JP];
Demandeur(s): SUMITOMO CHEMICAL CO [JP];
Classification: C01B7/04;B01J23/46;
N° de demande: EP20060767555 20060622 
Numéro(s) de priorité: WO2006JP312938 20060622;JP20050181607 20050622 
A rector for producing chlorine according to the present invention is a multi-tubular heat exchanger type reactor for use in producing chlorine by oxidizing hydrogen chloride with oxygen, characterized in that an interior of a reactor shell is divided in a tube-axis direction by a partition into a plurality of regions such that heat mediums individually circulate through respective ones of the divided regions; said reactor comprising a temperature control means for controlling the temperature of at least one heat medium selected from said heat mediums, the temperature control means being a cooler and/or a heater; catalysts having different catalytic activities are charged in the form of layers from inlets towards outlets of reaction tubes of the reactor, the catalysts being ruthenium oxide catalysts; and 40% or less of the whole ruthenium is in the region of the reaction tubes ranging from the reaction tube inlet to less than 50% of the reaction tube length, whereas 60% or more of the whole ruthenium is in the region of the reaction tubes ranging from 50 to 100% of the reaction tube length from the reaction tube inlet. A process for producing chlorine according to the present invention is characterized in that the process is carried out by using the above reactor, and comprises the step of supplying a hydrogen chloride-containing gas and an oxygen-containing gas into the above reactor so as to oxidize the hydrogen chloride with the oxygen at a pressure of 0.1 to 1 MPaG and a temperature of 200 to 500 °C.

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